在Flutter中,您可以使用`mime`包来获取未知扩展名文件的MIME类型。以下是一个示例代码:
```dart
import 'dart:io';
import 'package:mime/mime.dart';
void main() {
  String filePath = '/path/to/file';
  File file = File(filePath);
  String mimeType;
  // Try to get the MIME type based on the file extension
  mimeType = lookupMimeType(filePath);
  if (mimeType != null) {
    print('The MIME type of $filePath is $mimeType');
  } else {
    // If the MIME type cannot be determined based on the file extension,
    // try to read the first few bytes of the file and use that to determine
    // the MIME type
    List bytes = file.readAsBytesSync();
    mimeType = _getMimeTypeFromBytes(bytes);
    if (mimeType != null) {
      print('The MIME type of $filePath is $mimeType');
    } else {
      print('Unable to determine the MIME type of $filePath');
    }
  }
}
String _getMimeTypeFromBytes(List bytes) {
  String mimeType;
  List headerBytes = bytes.sublist(0, 12);
  // Use the lookupMimeType function from the mime package to get the MIME type
  mimeType = lookupMimeType('', headerBytes: headerBytes);
  return mimeType;
}
```
在上面的代码中,我们首先尝试根据文件扩展名获取MIME类型。如果无法确定MIME类型,则读取文件的前几个字节,并使用`lookupMimeType()`函数从`mime`包中获取MIME类型。
请注意,在调用`lookupMimeType()`函数时,我们将第一个参数设置为空字符串,因为我们不知道文件的扩展名。我们还将`headerBytes`参数设置为文件的前12个字节,因为这些字节通常包含足够的信息来确定文件的MIME类型。